I’ll chime in here with my recent experience.
I covered a Goldberg Sophisticated Lady with it. I had read that painting was problematic, so before I covered with the laminating film, I covered the model with colored tissue paper using glue stick and heat. It didn’t look as awesome as I hoped it would. The tissue paper by itself was neat looking, but obviously not functional. The laminating film went on great. It really reminded me of using any other iron-on type covering except you really have to crank up the heat to shrink it. Also, the final result isn’t as drum-tight as Monokote, but still plenty strong and adds plenty of torsional stiffness to the open frame wing panels etc. So my main takeaway from that experience was: tissue under doculam looks like...actually...it looks like doped tissue where the dope blushed badly due to extreme humidity. Not something I’m proud of showing off but definitely worth the experiment, and once it’s flying it looks just fine.
I’ve heard of doping tissue on top of doculam for the vintage look, but I’m trying to avoid the vintage stank.
I’m getting close to finishing a Cloud Dancer 40, and I plan to also cover this one with laminating film, then trying to paint it. It will be glow powered, so I’m hoping with proper prep Rustoleum will stick and stay. The other idea I’m kicking around is trying vinyl wrap material on top of the doculam, large color trim pieces and leaving some of the open framework clear.