I've been paranoid about lipos since I picked up my first mini-heli, a half dozen 130mah 1s cells and an accucell 6 about a year and a half ago which is what got me hooked.
My first few times charging I did it in our stainless steel sink. I figured for the little batteries even if they did catch the sink would be big enough to contain the fire.
When I got some 2s and 3s 500mah batteries for my first plane build (FT Nutball!) I started charging outside on a large piece of marble inside a cinder block. I also picked up a lipo safe bag from HK but I've seen videos of them catching and burning so I don't trust it and only consider it a second layer of protection - I mostly use it to keep charged and discharged batteries separated when I fly. After using a bat it goes into the bag.
When I built my Axon and got some 3s 2200's I dug out an ammo can (just a 30cal) and use that for storing and transporting - but still do the charging outside in the cinder block on the marble.
Haven't had any problems yet. But I'm pretty anal about my lipos (other than crashing with them) I stay within eyesight while charging so I can watch for escaping magic smoke, if I have to charge inside (106 outside today) then I do it in the lipo bag in the sink, I use a timer in my TX and a lipo monitor so I don't overdischarge....so far so good. Haven't puffed a battery yet. I did smash one 2200 into a fairly unrecognizable blob (riding in the nose of my axon while I learned ailerons!) it's still outside in the cinder block because it's still almost full voltage but I don't trust it - looks like one of the pouches may have torn but the full voltage on all cells makes me question if it's really a tear or not and one of these days I may try cycling it with a camera going just out of curiosity...but I'd do so outside in a bunker